71989-20-3

  • Product Name:Nalpha-FMOC-L-Glutamine
  • Molecular Formula:C20H20N2O5
  • Purity:99%
  • Molecular Weight:368.389
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Product Details;

CAS#: 71989-20-3

Molecular Formula: C20H20N2O5

Appearance: white to light yellow crystal powder

Quality Manufacturer Supply Wholesale 71989-20-3 with Efficient Transportation

  • Molecular Formula:C20H20N2O5
  • Molecular Weight:368.389
  • Appearance/Colour:white to light yellow crystal powder 
  • Vapor Pressure:1.47E-20mmHg at 25°C 
  • Melting Point:220 °C (dec.)(lit.) 
  • Refractive Index:-18 ° (C=1, DMF) 
  • Boiling Point:699.8 °C at 760 mmHg 
  • PKA:3.73±0.10(Predicted) 
  • Flash Point:377.1 °C 
  • PSA:118.72000 
  • Density:1.332 g/cm3 
  • LogP:3.33500 

Nalpha-FMOC-L-Glutamine(Cas 71989-20-3) Usage

InChI:InChI=1/C20H20N2O5/c21-18(23)10-9-17(19(24)25)22-20(26)27-11-16-14-7-3-1-5-12(14)13-6-2-4-8-15(13)16/h1-8,16-17H,9-11H2,(H2,21,23)(H,22,26)(H,24,25)/p-1/t17-/m0/s1

71989-20-3 Relevant articles

Novel chiral stationary phases based on 3,5-dimethyl phenylcarbamoylated β-cyclodextrin combining cinchona alkaloid moiety

Zhu, Lunan,Zhu, Junchen,Sun, Xiaotong,Wu, Yaling,Wang, Huiying,Cheng, Lingping,Shen, Jiawei,Ke, Yanxiong

, p. 1080 - 1090 (2020/05/25)

Novel chiral selectors based on 3,5-dime...

Optimized syntheses of Fmoc azido amino acids for the preparation of azidopeptides

Pícha, Jan,Budě?ínsky, Milo?,Machá?ková, Kate?ina,Collinsová, Michaela,Jirá?ek, Ji?í

, p. 202 - 214 (2017/04/06)

The rise of CuI-catalyzed click chemistr...

Fmoc-OPhth, the reagent of Fmoc protection

Yoshino, Ryo,Tokairin, Yoshinori,Kikuchi, Mari,Konno, Hiroyuki

supporting information, p. 1600 - 1603 (2017/04/03)

Fmoc-OSu has been widely used for Fmoc p...

A one-pot procedure for the preparation of N-9-fluorenylmethyloxycarbonyl- α-amino diazoketones from α-amino acids

Siciliano, Carlo,De Marco, Rosaria,Guidi, Ludovica Evelin,Spinella, Mariagiovanna,Liguori, Angelo

, p. 10575 - 10582 (2013/02/22)

The study describes a new "one-pot" rout...

71989-20-3 Process route

L-glutamine
56-85-9,26700-71-0

L-glutamine

Carbonic acid 1,3-dioxo-1,3-dihydro-isoindol-2-yl ester 9H-fluoren-9-ylmethyl ester

Carbonic acid 1,3-dioxo-1,3-dihydro-isoindol-2-yl ester 9H-fluoren-9-ylmethyl ester

N<sub>2</sub>-[(9H-fluoren-9-ylmethoxy)carbonyl]-L-glutamine
71989-20-3

N2-[(9H-fluoren-9-ylmethoxy)carbonyl]-L-glutamine

Conditions
Conditions Yield
With potassium carbonate; In acetonitrile; at 20 ℃; for 2h;
85%
L-glutamine
56-85-9,26700-71-0

L-glutamine

N-(9H-fluoren-2-ylmethoxycarbonyloxy)succinimide
82911-69-1

N-(9H-fluoren-2-ylmethoxycarbonyloxy)succinimide

N<sub>2</sub>-[(9H-fluoren-9-ylmethoxy)carbonyl]-L-glutamine
71989-20-3

N2-[(9H-fluoren-9-ylmethoxy)carbonyl]-L-glutamine

Conditions
Conditions Yield
With sodium carbonate; In 1,4-dioxane; water; at 0 - 20 ℃;
93%
With sodium carbonate; In tetrahydrofuran; water;
84%
L-glutamine; With N-cyclohexyl-cyclohexanamine; In acetone; at 20 ℃;
N-(9H-fluoren-2-ylmethoxycarbonyloxy)succinimide; With sodium carbonate; In water; acetonitrile; at 0 - 20 ℃; pH=8;
With potassium hydrogensulfate; In water; acetonitrile; pH=2 - 3;
54%

71989-20-3 Upstream products

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    L-glutamine

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    (9-fluorenyl)methyl pentafluorophenyl carbonate

  • 82911-69-1
    82911-69-1

    N-(9H-fluoren-2-ylmethoxycarbonyloxy)succinimide

  • 28920-43-6
    28920-43-6

    (fluorenylmethoxy)carbonyl chloride

71989-20-3 Downstream products

  • 71989-21-4
    71989-21-4

    Nα-fluorenylmethoxycarbonyl-L-glutamine p-nitrophenyl ester

  • 86061-00-9
    86061-00-9

    N-α-Fmoc-L-glutamine pentafluorophenyl ester

  • 133956-73-7
    133956-73-7

    Fmoc-Tyr(t-Bu)-Gln-Gly-Lys(Z)-OH

  • 161420-87-7
    161420-87-7

    Nα-(9-fluorenylmethoxycarbonyl)-L-2,4-diaminobutyric acid

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